Gas calorimeter



Oct. 21, 1930. 5 w, ARR 1,779,371

GAS CALORIMETER Filed March 9, 1926 4 Sheets-Sheet l ATTORN EY$ S. W. FARR GAS CALORIMETER Oct. 21, 1930.

Filed March 9, 1926 4 Sheets-Sheet 2 j BY INVENTOR 7?/M ATTORNEYS a-nmuuu '1' 5. w. PARR- GAS CALORIMETER Filed March 9, 1926 4 SheetsSheet 3.

INVENTOR ,kilm zvaw ATTORNEYS Oct. 21, 1930. s. w. PARR 1,779,371

GAS CALORIMETER Fi e rc 1926 4 Sheets-Sheet 4 w 7ILENTOR 47 W ATTORNEYS p Samoan ,w.

Patented Oct; 21, I 1930 assioi on, TO enemies-reign co ara vy,

se dee s-a s Ap neaaon'eieeir r-ch 9, less. serial naeaeos;

This invention relates to, gas calorimeters,

the principal objectoizthe invention being to provide an improved deviceformeasuring the calorific value ofany combustible gas, for example, ordinary producer gas. 1 The inven tion is capable of providing a continuous 1nd1- cation or record of theycalorific value of a COD'lbHSllllQlQ; gas supphedirom: any source.

ueof any combustible gas can be determined by. ascertaining its efiie'ctona bodyof l quid, such as Water; ,When the gas s burned inheat exchanging relation With the liquid. The

calorificvalue of a gas is ordinarily expressed Briti sh thermal units per cubic. foot ofvgas under certain definite conditions of'tempera tur'e andpressure. The B.;tj. n. has been-deg;

fined as the quantity of heatrequired to raise the temperature of one poundof. pure Water: one Fahrenheit degree. It is therefore ap parent that ifa cubic foot of gas under stand-K ard conditionsof temperature and pressure (say 60 degrees Fahrenheit and30-inches 0f-v mercury) be burned under, a cubic 1 foot of Wateiythen;neglecting radiationlosses, the calorific'value oithega's expressed in B. tgu,

per cubic foot is equar to thechange in ,temperat Fahr produced by the combustion of the gas When certain volumes of the gasare burned so as to deliver their heatunits to equal volumes of Water.

One of the principal objects of this invention is to provide a calorimeter in Which equal volumes of gas are burned under equal volumes ofwater atconstant temperature and 1 a are whereby the calorific valueof thegas can bedetermined by applying a singlefac.

tinuous flow of gas to the burner'oif-this heat- The flow of Water and gas is controlled in suca a manner that the volume of Water e of the Waterexpressed-in degrees cit multiplied by the- Weight of a cubicfoot of Water, ltisalso true that the calorific value of a can be ascertaineddi rectly by noting the temperature change suppliedto the heater is equal to, or. bears a predetermined relation to, the volume of gas supplied to i the heater, and meansare pro? videu torinsuring a constant temp-erarture and While the improvedcalorimeteris prefer;-

umes of'gas andfwater, it is to be noted-that the quantity of gas or of waterpneed not be ascertained in order todetermine-theJCalO- IlfiC value of the gas. In otherwords, iniordertodetermine theacalorific value of .thef

gas, itrflis not necessary to determine the amount or quantity of gas or .of'vvater pass.-

ingtlirough-the'calorimeter; The quantity of V 7 gas can he ascertainedif this isgdesirechbut I it isnot necessary toascertain this-factor inv order to determine the calorific valueof'the: gas. The embodiment of the invention hereinafter de'scribedflin detail includes means,

for raising the temperature of the lvvaterto.

a certain. predetermined value prior to theentrance 7 of this Water. i'ntothe heater Where in its temperature is raised by the gasgbeing tested. The yvater may be preliminarily heat;- ed by any sultable means but Iprefer tQLQHlT ploy a gas burner for this purpose and to control the supply of gas to thisqburner by means responsive tothe tcmperatureof the V preheated Water, thus insuring Constant temperature. This embodiment oftheinven tion alsoincludes means for bringing the gas to be tested into heat eXcha-ngingrelation. With the preheated Water, so thatthe tem- 1 perature of the gas is raised to approximately the-Iteniperature oi? the preheatedlwater. The improved ClQVICQ also includes apressure regulator for controlling the flow of the gas which has bee heated in the manner just described.

pressureof the gas so supplied to theburn? ably constructed so asto deliverequalavol It Willbe appreciated thatthe heating .val'- An improved part of this'inv'entioncomgas inlets or ports of these tWocont-ainers and the burnerwvhichburns the test gas, and there is also a pipe connection'to the source of" heated or] conditioned gas 'described; above. This valve and the. pipes prises two containers eachhaving a Water] inlet and a gas inlet. A valve and; suitable pipe connections areprovided betvveen the communicating therewith are so arranged that at one instant the gas port in one of the containers is connected to the burner and the gas port in the other container is connected to the supply of conditioned gas. 7

A valve and a plurality of pipes, similar to the valve and pipe connections just described, are arranged so as to connect the water inlets or ports of the two containers with the water heater and with the source of preheated water. The water heater referred to is the one to which heat is supplied by the burner which consumes the test gas. This last mentioned valve and associated pipe connections are arranged so that at one instant the water port in one container is connected to the water heater and the water port in the other container is connected to the source of preheated water. The water and gas valves just described shouldbe actuated in a.definite timed relation and it is entirely feasible to actuate these valves by a single means, although of course separate means can be employed for this purpose. The two valves may be arranged to operate in such a manner that at one instant water is being supplied to the heater from one of the two containers, while gas is being supplied to the burner from the other container. After the major portion of the gas in the container has been supplied to the burner, the gas and water valves may be operated so as to reverse the connections and supply water to the heator from the container which previously supplied gas to the burner and to supply gas to the burner from the container which previously supplied water to the heater. Some means, such as a float switch connected in circuit with an electrical device for actuating the gas and water valves, can be used for controlling the change in the connections between the containers and the other parts of the device.

This invention includes an improved heater in which the water is heated by the gas being tested. This heater is constructed in such a manner that there is a very etficient transmission of heat to the water. A mixing chamber is provided in fairly close proximity to the heating chamber, the purpose of this mixing chamber being to thoroughly mix the heated water prior to its coming in contact with the temperature sensitive element which serves to indicate or record the temperature of the heated water. An improved feature of this mixer is a device for supplying air to the stream of Water flowing into the mixer. The stream of water entrains some of the air and the air bubbles serve to effect a thorough mixture of the water within the mixing chamber. It is preferred to have this air supply under control so that by adjusting the air port the rate at which water flows into the mixing chamber can be ad usted, as well as the amount of air discharged into the mixing chamber.

One of the improved features of this invention is the means for actuating the water and gas valves mentioned above. It is desirable to operate these valves in definite time relation and it is satisfactory to have the valve mechanism constructed in such a manner that rotation of the valve through 90 effects the necessary change in directional flow of the gas and water. The improved valve actuating mechanism includes means for locking the valve member or members as the case may be, against accidental displacement, means for unlocking the valve member, means for rotating this member through a predetermined angle, and means for again locking the member in the new position. According to this invention, this series of operations is performed by a single motor connected, in a manner hereinafter described, to the valve member and to the locking means for this member. This motor can be arranged so as to be started and stopped by the float switches described above as being arranged within the two containers which are alternately filled with water and gas.

The various objects and advantages of this invention can be best understood by considering the following detailed description, which is to be taken in conjunction with the accon'ipanying drawings, in which Fig. 1 is a perspective View (largely diagrammatic) of one embodiment of the improved calorimeter; Fig. 2 is a diagrammatic. flow sheet illustrating the operation of the embodiment of the invention shown in Fig. 1; Fig. 3 is a vertical section view of the water preheater; Fig. 4 is a vertical section View of the water and gas valve mechanism and the means for actuating the same; Fig. 5 is an elevation of the parts shown in Fig. 4; Fig. 6 is an elevation, partly in section, of some of the parts shown in Fig. 4; Fig. 7 is a vertical section view of the heater and the mixing chamber associated therewith; Fig. 8 is a transverse section view of the heater taken on line 88 of Fig. 7; and Fig. 9 is a vertical section view of the gas pressure regulator.

As pointed out above, the improved calorimeter includes means for preheating a continuous supply of water and a continuous supply of the gas to be tested. The pressure of the gas is carefully regulated so that the gas is delivered under conditions of constant tem perature and pressure. Equal volumes of water are heated by equal volumes of the gas to be tested and this process is carried out in a substantially continuous manner. The calorific value of the gas is at once determined by means responsive to the difference in tem- 'perature between the preheated water and the water which has been subjected to the heat of the burning test gas.

nember water from/the tank 6 to thewater valve shown at.10,and.pip.es 11 and 12 extend hetween the valve housn and the co s 13 and 14.; Water s'ar. rnately idel qeredto the containers 13and 14 under; the control of the'val ve1OQ p 1 7 ,7 p

The gasto he tested entersthe heating'coil 7 within the tanl rfi througha suitaolepipe connection 15. The gas flowi'ng' this coil 1'? is brought to a temperature approximately the same as that of the preh ated water which is supplied to the tank 6 by the pipe 5. The gas leaves the coil 7 throu A p 6, through a pressure regulator 17 and ti n apipe 18 tothe gas valve 19. 21 connectthe housing of ti co tainers l8 and 1 1 respectlvely and k is alternately supplied to these two containers ier thecontrol of thevalvela; Apipe 22 connects thevalvc 19with a hurnery23 and a pipe 2;:con'nects the water ;1Q,wifth a heating tank :25. The gas to he tested ishurnedrin the burner 7'33 and supplies its t m water v within the tank A; then may he used for the purpose or n'ieasuring or idicating thewat er entering the tank 25, a thermometer 2? may he used 1" e purpose of in heating the temperature of the water at er it has left the container 25 though the iniXin chainher after coming in Contact with the temperature,

)onsive element 2-77 maypass oi'tito a suit-- le drain through a pipe 29;

V The method of operation ot theucalorinietercan he 065i;URdBXStOOCldDyQfiFStCOnSldBlF ing the manner in which gas and water flow through the system when the valves 10' and.

19 occupy thepositionsshown in The ,water which has been brought toa pre-L- Y and which has brought the temperature or the to suhstantiallythis same temperature, is free to :flow through the pipe con-:- nection 9, valve housing 30 and pipe12, into the container 1%. At thesame time, water whichhas been previouslyr'supplied to the determined temperature in the preheate;

container -13is now treeto flow through pipe 11, valvehousing 30, and pipe 2 i to the heaty er 25. While this is tak ng place,igas, which has, previously been supplied to container 1:

and l ich is now being forced out of thisicontainer the temper ature of c a snniiar passed the system.

by "the water entering the I container,

through pipe 12,fl0ws through pipe 21, valve housing-31 and pipe 22to the burner 23. At

the same time, gas from the coil 7 is flowing through pipe 16, pressure'regulator 17, pipe 18, valve housing 31 and pipe 20, into the con tainer 13 to taketl e place oi": the water which is flowing; out of this container and into the .7 25. It is thusapparent that the gas which occupied container 14 is being utilized heat the ater whlch occupied container 2S co nues until the water entering er 14 rises to a predetermined level therein and actuates a float switch 32. This closes a control ci it for the motor 33 and as soon as power s suppliedto this motor it operates to rotate valves 10 and 19 through an an gle of thus reversing the connectioi'is to the containers l3 and 14;. happens, the water which has just flowed into the container 1 1- is now free to flow in the opposite direction through pipe 12, then through so that the supply ofgas to the burner 23 is not appreciably interrupted and the fianie is not extinguishedi Similarly, the flow-of wa ter through pipe 26% tothe heater 25 eniains substantially constant;evenmthough at one instant the water is heing supplied from container l3and then as soon as the valve 'i'necha-V nisin operates troi'n'the other container 14. The difference in the indications; of the two thermometers 26 and 27 gives a measure of the calorificvalue of the gas'suppliedto the: burner 23 and it is evident that this indication or record is entirely independent of the" quantity of gas or of water passing through It is' notnecessaijv; that t ofi'low of the gasfshould heany predeter' mined value; it is merely necessary that the volume of under predetern i e conic tionsof temperature and pressure should hear a definite relation to the volume of water.

It is preferredthat thevolum'e of gasshould heequal. to the volume of water. It is not necessary to-have the containers'lB and 1.4; of the same SlZQflIlflSlllllCll as gas i roin one of these containers is used' to heat waterfrom the other and then the process is reversed so that the complete cycle it is inevitable that equalquant ties of are used toheat equal.

quantities of water. 7 a c; i a lt will be understood that when thepositio'n of valve 10 issuch that waterca n flow tlirou 'h pi cs9 and 11 into the container 13 the level of the water rise ,in this container untilit actuate s floatswitch 33 similar to the float switch 32 in container 14. As soon As soon as this Thus gas from container 13 is now being used Cit as this happens, the motor is again actuated to turn the valves 10 and 19 through another 90 to again reverse the connections to the containers 13 and 14. The calorimeter thus continues to operate and the thermometers 26 and 27 give a continuous indication of the temperatures of the water before and-after passing through the heater 25. If it is so desired, a differential recording device 34 of any well-known construction can be connected by means of the connections 35 and 36 in such a manner that the device is responsive to variations in the diflerence in temperature between the water flowing into the heater 25 and the water flowing out of the mixer 28. In this way a permanent record 01" the calorific value of the gas can be obtained, and the device can be calibrated so that the calorific value can be read ofl directly in terms of B. t. u.s per cubic foot of gas.

Having given a general description of the manner in which the several parts of the im proved device cooperate, a detailed descrip tion will now be given of each of the co1n ponent parts of the device.

The water preheater The water preheater 1 and associated parts are shown in detail in Fig. 3. This figure shows a water receptacle 37 communicating with the inlet pipe 2 and with the outlet pipe 5. This receptacle is surrounded by a jacket 38 adapted to receive the hot gases from the burner 3 and conduct them up along the side of the water receptacle 37. A plate 39 forms a cover for the water receptacle and its enclosing jacket 38 and is provided with a plurality of openings or vents 40, through which the gases from the burner may ultimately escape. The water receptacle 37 is mounted on a suitable base 41, and the burner 3 is located directly below the water receptacle 37, so that the flame impinges against the bottom of this receptacle and the hot gases rise up around the receptacle. The pipe 4 supplies gas to the burner 3 and this gas is under the control of a valve 42 operated by a thermostat 43. This thermostat may be located within a suitable housing 44, extending down into the water receptacle 37 and the thermostat may communicate with a suitable gas or air chamber 45, also disposed within the water receptacle 37 When the temperature of the water within the receptacle 37 rises beyond a predetermined value, the air or gas within the chamber 45 expands and the valve 42 is forced against its seat so as to restrict or even entirely prevent gas from flowing v through the valve to the burner 3. The gas is supplied through a pipe 4 and then flows down through a short passage 46 into the valve chamber 44. It escapes from this chamber under the control of the valve 42. It is desirable to have a restricted by-pass opening 47 leading directly into the pipe 4 from the pipe 4, so that at all times there is at least a small amount of gas being supplied to the burner 3. This prevents the flame from being extinguished when the Valve 42 closes.

It has been found that this preheating device is very sensitive to slight changes in temperature and it is possible to control the temperature of the Water flowing out of the re ceptacle 37 so closely that the variation is not more than 2 to .5 C. The operation of the valve 42 can be made extremely sensitive by providing within the chamber 45 a small quantity of a liquid having a boiling point approximately equal to the temperature which it is desired to maintain in the stream of water flowing out of the receptacle 37. It will be understood that whenever there is a tendency for the temperature of the water within the receptacle 37 to rise beyond the boiling point of the liquid within the chamber 45, considerable vapor is suddenly produced within this chamber and the valve is suddenly closed.

The temperature equalizer As pointed out above, this invention contemplates the provision of some means for raising or lowering the temperature of the gas which is to be tested, to bring the temperature to some predetermined value. It will be understood that any suitable means may be employed for this purpose, but it is preterred to utilize the preheated water after it passes out of the preheater 1. A suitable de vice for bringing about this result comprises the tank 6, into which the water is discharged through the pipe 5 leading from the preheater 1. This tank is provided with an overflow vent pipe 8, which serves to maintain a constant water level within the tank 6. The gas which is supplied through a pipe 15 passes through the temperature equalizing coil 7 within the tank 6, and then passes through the pipe 16 to the pressure regulator 17. In this way the temperature of the gas is brought to a value substantially equal to that of the water in the tank 6.

The gas and water containers The containers 13 and 14 mentioned above are adapted to receive the preheated water from the tank 6. This water flows through the pipe 9 to the valve housing 30 and it then flows alternately into containers 13 and 14 under the control of the water valve 10.

In the embodiment of the invention illustrated in the accompanying drawings, the two containers 13 and 14 are of substantially the same dimensions and configuration.

The container 13 has an enlarged portion 48 in open communication with an elongated upright portion 49. The container 14 has a similar enlarged portion 48, communicating with an upright portion 49 of smaller diamczi eter. 1 A float50is provided within the por tion 49 of container 13 and a similar float 50" is provided in the portion 49" of the other container 14. These two-floats are connected by suitable; linkages to the switches 32 and 33, guides 51 and 51 be1ng provided for the purposes of insuring true vertical movement of the floats 50 and 50'. The switches 32 and 33 may be of the ordinary mercury type ar ranged in such a manner that when the switch occupies one position, current may flow be tween the contacts ofthe switch through the mercury. The'switch32'is shown in this po sition. When the switch occupies a position such asthe switch 33 occupies inFig. 2,: the circuit 1sbroken.-The contactsof the switches 32 and 33"are connected in'parallel.

by means of leads52, 53, 54:,and 5,5. l

The floats 50- and 50? which control the operationpof switches 32'and 33, are pref- .erably arrangechwithin ltheelongated upright portions 4; 9 and l9 of. the containers 13' and 14-, in order that the operation of the f switches be critical, It will be understood that a small changeiin the volume of the liquid supplied to either of these containers will produce a correspondingly large change in the level 'ofthe liquid within the elongated upright portions of thesecontainers. r

The moi/01" 0mm; system I i The operation of themotor. 33, which actuates the water and gas valves and 19, is commueab thefloat switches 32 and 33, located, in the-upper portions of the con} 'tainers 13 and 14. These switchesare elecs trically connected inparallel'and serve to make and break-acircuitwhich includes the relay 56. Vvith switch 32in the-position shown in Fig. .2, the relay circuitis closed,"

the circuit being as follows: source'of current 57, lead 58,coil 59,.Qolfrelay '56, lead 60, thermal relay 61,- contact 62, lead 63, lead 54, switch 32, lead 515, and leadtb ackto thesource of current 57. The operation of.

V coil 59 closes a circuit forthe motor 33, this circuit being as follows; supply leadf65,

relay contacts 66, lead 67, lead 68,"and supply lead 69. When this "circuit closed,

supplied throughfleads 71- and 725 A lamp, or other resistance unit'73may be connected this is so desired'.

current is supplied to the heating element "(O of the thermalrelayjGLthis current being in series 7 with the .heatingelement- The'float switches "32 areclosed alternately due togthe flowfof liquid into first one of the containers 1 3 and and thenjinto the other, andit will be under stoodthat the closing of either one of these switches causesthe motor 33 to"; operate, and this motor in turn actuates the gas and water valves 19'1an'd 10 respectively to re verse the connectionstofthe containers 13 i and M."

" The water' Zieater The water heater shown at in Figs; 1 and 2 isshown in detail in Fig. 7. This heater comprises a jacket or outer shell 74 connectedto a base member 75. A closure plate 76 is provided atthe top of the jacket A' liquidinletis shown at 77. This inlet communicates with the chamber 78 which iS 1I1 direct communication with the.

pipe :24, which is connectedto the housing 130-of the valve 10. The sensitive element cf the hermometer 26:01 equivalent device may be arranged withmthe chamber- 78 so that it will-,beresponsive to the temperature of the'water passing-through this cham .ber,

A plurality offlues are provided within: the water jacket 74 for the purpose of conducting'hot gases fromtheburner 23 into eiiicient heat exchanging relation with the Water; in the jacket 7 i. The arrangement of: fines shown in Fig. 7 includes a central flue 7 9 arranged directly above'the tip of the burner 23. A plurality-of'tubes 80' are ar- 7 ranged around this central flue T9 and communicate therewith through a header 81.

his header'cont'ains a plurality of vertical plates or partitions best shown at: 82 in Fig.

8. These plates serve to guide the hotgases into thef-tubes 80. It -is desirable to provide a bafileplate 83 at the upper endof the flue 7 9 and separated short distance from the inner surface ofthe header' SL. This bafiie plate may rest on notchedportions of the plates-82asindicated in Fig; 7.- Where thisbaflle-plate is not provided, thereis a tendency for condensible .products of com bustion to collect on the surface of the header sl, directly above the burner 23. V.

to preiient condensation of any ofthe constituents "of the flue gas at points-directly above the burner It Will benotedtl at the hot gasesiand water flow, in countercurrent "relation within the heater. 7

A collar 84c'is provided around the tip of l theburner 23, the diameter of this collar being somewhatflar'ger than that of the burner tip, so as to permit air to flow up along the b urner and thus supply the required, oxygenfor combustion of the gas: This collar-Saintly beformed' soas'to provide an annular channel or manifold 85 V communicating with the lower ends of the verticaljtubes 80. A ventispout 86 communicates withthis manifold and servesias a means for disohargingthe flueg'ases from the heater after they have passed up through the flue 79 and down through the tubes 80.

. Thisspout'also serves to discharge the water which collects within the tines as a result of the Combustion gases coming into contact withthe-relatively cold walls of these flues. Inthis connection it may be pointed out that a graduated container 87 may be provided for the purpose of collecting the condensate dis charged through the spout 86. By ascertaining the amount of the condensate formed while a measured quantity of gas is being burned in the heater, it is possible to compute the amount of heat which is liberated in form' ing this condensate. The heat of vaporization of this condensate may be thus taken into account in ascertaining the net heating value of the gas supplied to the burner 23. A fine 79 ispreferably provided with an enlarged lower portion 79 forming a combustion chamber of sufficient size so that the burner flame does not come in direct contact with the inner surface of the fine. This prevents the formation of deposits of carbon Within the fine and it prevents incomplete combustion of the gases.

The mixing chamber The mixing chamber shown diagrammatically at 28in Figs. 1 and 2 is shown more in detail in Fig. 7. This chamber is connected to the water heater 25, just described, by pipe 88. This pipe, or a continuation thereof, is provided with an outlet 89 disposed at a certain level within the receptacle 90. I prefer to construct the outlet for this mixing chamber in such a manner that the outlet pipe communicates with the interior of the chamher at a level above the outlet of the pipe 88, for example, as shown at 91. This outlet pipe 92 may extend in a downward direction to a level near to or below the bottom 93 of the mixing chamber 28. This is clearly shown in Figs. 1 and 2. The container 90 is closed at the top by a suitable plate 94 and it will be understood that the arrangement of the pipes 89 and 92 of the container 90 is such that 'a siphoning action is produced. Any

collecting in the upper part of the container 90 is drawn into the pipe 92 by the liquid escaping through .this pipe and in this way a partial vacuum is created within the container 90. This, of course..has a direct effect upon the flow of liquid through pipe 88 into the mixing receptacle 90. A removable plug '94 is providedin the cover plate 9%, directly above the outlet pipe 92, to permit readyaccess to this pipe for cleaning the same.

.I have found that by providing an air port communicating with the pipe 88, it is possible'to admit a restricted amount of air to the stream of liquid flowing into the mix, ing chamber. This air portalso serves a useful function when the system is first started up, in that it' permits the escape of any air which may become pocketed in that portion of the system adjacent to the air vent. This air port serves other important functions which will be pointed out below.

At 93, in Fig. 7, I have illustrated a T connection in the pipe 88 and it will be noted that a short piece of piping 94 communicates with this connection and is provided with a cap 95 having an orifice 96 in the end thereof. A valve 97, having a hand lever 98, can be used for controlling the entrance of 'air into the pipe 88. Ithas been found that if the valve 97 is wide open so that the maximum amount of air can flow into the pipe 88, the flow of liquid through pipe 88 will be retarded to a considerable extent.

Furthermore, by adjusting the valve 97 to' any desired position, the rate of flow of the liquid through pipe 88 can be regulated accordingly. Thus the air port and the valve for controlling the flow of air serve as a convenient means for regulating the flow of liquid into the mixing chamber 28.

Not only does the air connection just described serve as a means for controlling the flow of liquid, but it also serves as an eflicient means for agitating the liquid within the receptacle 90. The air is carried into this receptacle after it has been entrained by the stream of liquid flowing through pipe 88 and it has been found that this air in bubbling up through the liquid in the receptacle 9O agitates the liquid thoroughly. Accordingly, all variations in the temperature of the liquid flowing through pipe 88 are smoothed out or obliterated within the mixing receptacle 90 and the temperature of the liquid flowing out through pipe 92 remains con stant, unless, of course, the average temperature of the liquid supplied to the container 90 changes. The pipe 88 by projecting down into the body of liquid within the receptacle 90 causes the air entrained in the stream of liquid to bubble up through the body of liquid and agitate the same. While other means for agitating the liquid might be employed, yet I prefer to utilize for this purpose the air which is admitted through the orifice 96 and which also serves to regulate the flow of liquid through pipe 88.

The liquid in passing out of the container 90 through the pipe 92 flows into a small chamber 99 adapted to receive the sensitive element of a thermometer or equivalent device 27 y The valve operating mechanism In Figures 4:, 5 and 6, I have illustrated in considerable detail one embodiment of the means for actuating the water and gas valves shown at 10 and 19inFig. 2. It is convenient, although not necessary, to have these two valves connected to or operated by a common member; this insures operation.

nection with Fig. 2,'it Will be understood that mem er 101 constructed so to form Waterand gas valves '10 and 19 respectively. The valve housing 100 isprovided With a tapers-t bore, and the valve member 101 15 of similar configuration. A spring 10:2 13511- ranged so to hold the valve member in 1 J. v place Within the tapered bore of the housing 100, and an adjustable set screw 102 arranged so as to prevent the spring 102 from causing the valve member to become lodged in its seat. r

From the description given above in conthe connections to the containers 13 and 1 1 can be reversedby rotating the valve memher 101 through an angle of 90. It is desirable to have some means forrotating this valve member and this means should be under the control of the float switches in containers ;13 and 14:. The motor 33 is adapted to rotate the valve member 101 and, as pointed out above, the operation of this motor is controlled by the float switches 32 and 33. This motor serves to not only. rotate the valve 101,-but-also to lock this valve in its new position andto release the valve when it. is necessary torotate the valve. through another angle of 7 Figures 4, 5 and 6 shows ratchet Wheel 103 fixed With respect to a pulley 101 and both of these elements are keyed or otherwise fined tolfthe valve member 101. A1belt1105connects the pulley104 vvitha driving pulley 106 loosely mounted on the shatt 1070f the motor-33" A spring 1O8 has one lend-thereof fined tothe shaft 107 andth'e other end fixed to the pulley 106 and thesmotor transmlts power to thepulley 106through thiss'pringi The. teeth of the ratchet wheel'103 cooperate with a dog 109., mounted on'a stub shaft 110. This dog .isfixed With'respect to a pulley 111 and this pulley-is connectedtoa driving pulley 112 by means of axbelt .113. a

A pin or abutmentll lpro-jects from the.

side of the pullev 112 and cooperates .With a similar pin or abutment, 11 5 fixed to the motor shaft 107. Accordingly. powercan be transmitted to the pulley through pins ll and-115. f 7' lows 5 tliefirst eliectot' the motowhile the; pulleys 106 and 112. remain -sta tionaryr Theratcl'iet v'vheel 103;is lOCliEdnntl this prevents-the-pulleys .,106:and 11251 1 0111 rotating at the start. It 'isgonly -When the pins lleandlldcome into engagement with eachv other that p the pulley; 112 is caused to;

making it out'ot alcoiledspring; v p p My improved means f or actuating the .n

rotate. This causes the pulley 111 to rotate through a small angle and disengage the locking projection 116 fromthe ratchet Wheel 103. The pulley 104i new tree to turn and until rotation of the ratchet Wheel 103Ii's arrested by the abutment 117 (see l 6) forming a part of the dog 100. Further rotation of the dog 109 and of the ratchet Wheel 103 are thus prevented and the belt 113 commences to slip on the pulley 112. This slippingfmay be localized at this pulley by providing a pin 118 passing through the belt I 113 and into the pulley 111., lVhen rotation of the pulley10 l is arrested in the manner just described, continued'rotation of the motor 33 serves to Wind up the spring 108 to an. even greater extent and ultimately the belt commences to slip. By tl'iistime the operation of the motor 33 .is interrupted dueto the operation of thejfl'oat switch in one of the containers 13 and 14: (see Figs. 1

and As soon as the current supplied to the motor 33 is cut ofit' the sprin'g"108 is vfree to recoiland this action of the spring serves to rotate the motor shaft in the directionopposite to that in which it vas previously rotating. This causes the dog 109fto rotate'so as to separate the abutment 117 from the ratchet Wheel 103 and to force the projection 116 into an adjacent toothof the ratchet Wheel. These parts arepreferably so constructed anderranged that as the pro:- jection 116 enters the tooth opposite the'same. the ratchet Wheel is forced around or ad- Vanced through a small angle and the ratchet. wheel is then locked in this new position. Thisconstructionis desirable because it preventsthe. abutment 117mm engaging the same tooth of the ratchet WhBCltWlCe in'succession. It'the float switch fails to operate, the thermal relay 61 operates" to break" the motor-:ci1'"cuit.;-v 1

' The motor 33' not onlyrotates the valve -member 101, but it causes this valve member to be locked in its new position and it also servesto release the valve member v' henf itl is desirableto have it rotate through another i a an le to a ain chan ethe connections tothe The mode note erat on of the valve aetu h c g sting fmechanism gbel described as fol containers 13 and. 1 1 above described. The operation of the spring 108 in reversing the:

With the motorl33 thedirec- Of'the @1031109 canbe tionind-icated by thexarrows infFigs. p 7 o rotate the i ,motor shaft through, approximately made morelpositive' making the belt 105 out of'resilient material such as rubber, or

valve member 101 has been found to be very reliable; it causesthevalve member to be rotated very quickly througha complete an gle of. exactly 90 and thevalve member is efiectively'locke'd in this position against ac- Cit cidental displacement until the dog 109 is actuated so as to release the valve member and permit continued rotation thereof.

Method of operation In the particular embodiment of the invention illustrated in the accompanying drawings, Water or some other suitable liquid is supplied to the container 1 through a pipe 2. This device serves the purpose of bringing the temperature of the liquid to some predetermined value. I have shown a burner 3 for raising the temperature of the liquid to a predetermined value, gas being supplied to this burner under the control of a thermostat located within the container 1. A pressure regulator 4 may control the supply of gas which is ultimately burned in the receptacle 1 and a pressure regulator 2 may be used for the purpose of regulating the pressure of the liquid supplied to the container 1. The liquid, after having its temperature brought to a predetermined value, then flows into a tank 6, where it comes into heat exchanging rela tion with a coil of pipe 7 through which the gas to, be tested flows. The tank 6 and the coil 7 may be considered as a means for equalizing the temperatures of the gas and water or other liquid passing through these parts of the apparatus. The gas and liquid are then supplied alternately to each of the containers 13 and 14 under the control of valves 10 and 19 which are operated by the motor 33. Hand operated valves 11 and 12 may be used for independently regulating the flow of liquid into each of the containers 13 and 14.

A pressure regulator 17 controls the supply of gas to the containers 13 and 14. The details of a suitable regulator for this purpose are shown in Fig. 9. This particular device comprises a housing 119 enclosing a collapsible pressure chamber 120. The interior of this chamber communicates with the atmosphere through a pipe 121 having a valve 122 therein which can be used to close this connection completely it this is desired. A lever 123 rotatably mounted on a. suitable support 124 operates a valve 125 which controls the flow of gas from pipe16 into the housing 119. One side of the pressure chamber 120 is connected to a lever 123 by means of links 126 and 127. It will be understood that as the gas pressure builds up within the u housing 119, the pressure chamber 120 is compressedand the valve 125 closed.

The liquid which is-supplied alternately to containers 13 and V 14' actuates the float switches 32 and 33 and the switches in turn control the operation of the valves 10 and 19. The liquid flowsout of the containers 13 and 14 into the heater 25 through a pipe '24, and in like manner the combustible gas flows out of containers 13 and 14 to the burner 23 through pipe 22. It will be understood that the gas is forced out of containers 13 and 14 by the liquid flowing into these containers from the tank 6. The rate at which gas flows out of containers 13 and 14 and consequently the rate at which liquid flows into these containers is determined by the adjustment of the valve 128. By opening the valve 128. the rate of flow of the gas can be increased and consequently the liquid flows into the containers 13 and 14 at a faster rate. The rate at which liquid flows out of containers 13 and 14 can be controlled by regulating the supply of air to the pipe 88 which connects the heater 25 with the mixer or temperature equalizer 23. The rate at which liquid flows out of containers 13 and 14 determines the rate at which gas flows into these containers through the pressure regulator 17. It is desirable to have the heater 25 so located with respect to the containers 13 and 14 and the valve 10 that liquid stops flowing out of the containers 13 and 14 even before the valve 10 is turned so as to establish communication with the liquid supply pipe 9. It is desirable to have the heater 25 arranged so that the level of the liquid therein is somewhat above the valve 10. These parts are not shown in this position in the accompanying drawings because of the difficulties involved in showing the parts in this desired relation to each other, and of course this desirable result can be accomplished in ways other than that just described.

Inasmuch as liquid stops flowing out of say container 13 before the Valve 10 operates to connect this containerto the liquid supply pipe 9, it will be apparent that the gas pressure within container 13 has an opportunity to build up before the valve 10 operates. This pressure builds up until the supply of gas is cut off by the pressure regulator 17. The improved device thus provides means whereby the gas can be supplied to containers 13 and 14 at a substantially constant predetermined pressure, and furthermore the temperature equalizer represented by the parts 6 and 7 makes it possible to supply this gas at a constant predetermined temperature.

While it is not necessary to determine the quantity of either the gas or the liquid passing through the system in order to determine the calorific value of the gas, yet it is entirely feasible to determine the quantity of gas or of liquid or both passing through the system. The containers 13 and 14 and parts associated therewith serve to isolate or measure ofi equal volumes of gas and liquid under constant conditions of temperature and pressure, and in order to determine the total amount of gas or liquid or both passing through these containers, it is merely necessary to measure the capacity of each and to ascertain the number of times each is filled with gas and liquid. By determining the number of revolutions of the valve member 101, it is possible to-ascertain the quantity of gas orliquid or both passing through the system, because for every revolution 'ofthis valve member, a definite quantity of gas and a definite quantity of liquid pass throughthe container; 13 and 1.4. Acco'rdingl-ya revolutien counter connected'to the valve member 101 can be used as a'means for measuring the quantities of the fluids passing through the system. I have illustrated such a counter at 129 in Figs. 1,2 and4; Thisdevice may be provided with scaleswhich cooperate with a suitable pointer to indicate directly the quantity of liquid passing threugh the sys tem and the quantity ofgas passing through the. system. I.A.ccorclingl.y, my improved de vicefca'n be used as a gas meteras Well mean'sfor determining the calorificvalue of a combustible gas. Where it is used merely.

for the purpose of measuring the quantity of gas,-it isof' coursenot necessary toburn the gas; in the burner 23-; it can b'esupplied to a gas main through: apipe 130, as indicated in Fig.1. 7 Furthermore, it is not necessary to heat the liquid Where the 'device' is usedmerely as a: means, for measuringthe quant ty of a fluid passing through thejsame. The liquid maybe Withdrawn from-the 'con-.

tainers-18 and llthroughaJpipo 131 and brought back to the supply pipe 2 by some suitable means suchas a pump; 132.

The thermometers 26 and 27 can be used as a means for indicating the temperatures of the Water as it fiows into the heater'25 equalizer 28. In order th ata permanent record of the calorific value of the. gas maybe I obtained, a recording instrument 34 of any ord nary construction can be connected, as lndlcated n Figs. 1 and 2. This instrument operates as a difierential temperature recording device anddnay be calibrated so. as to indic'ate the 3 calorific value of the gas. This instrument may be locatedclose to the heater 25-or at someremotepoint, and oiicoursea plurality of such instruments can be employed and located at Various points, if this is so desired. y 7 7 It is to beunderstood that myinvention not limited to the particular embodiment, illustrated and described, but includessuch modifications thereof as fall Within the scope of'the appended claims. ]The details of construction and-the arrangement of the various parts can be varied Without departinglfrom- 1. a device type; described, the:

combination .ofa liquid container, a gas burner for supplyingheat'rto liquid in s'aid container, means for supplying a volume of liquidate saidv containery and means for respectively; l

bringing a gas to a predetermined temperature and pressure,meansfor supplying to said burner a volume of said gas bearing a predetermined relationto the volume of liquid supplied to said container.

, '2. In a device of the type-described, the combination of a liquid container, a gas burner for supplying heat to the container,

means for bringlnga gas to a predetermined temperature and pressure, and means for supplying equal volumes of liquid and gas to the containerand burner respectively.

3. In a device of the type described, the combination ofa liquid container, a gas burner for supplying heat tofthe container to raise the temperature of the liquid therein, means for bringing -a gas to a predeter-- mined temperature and pressure, means for supplying equal volumes of liquid andgg'as to the container and burner respectively, and

indicating means responsive to changes in temperature of the liquid in said container, T

4. Ina device of the type described, the combination of a liquid container, a] gas burner for supplying heat to the container, means for, bringing a gas to a predeter- Vmined temperature and pressure, and means for continuously supplylng equal volumes of liquid and gasto the container and burner 5. In a device of thetype described, the combination of a liquid container,'means for supplying heat to liquid in said container,

means for continuously supplying liquid to and as it, leaves the mixer or temperature said container, amixingreceptacle "comjmunicatlng Wltll said contalner and having a liquid outlet, means for agitating the liquid in said rece'ptacle'and indicating means responsiveto the temperature of the liquid before it hasbeen heated in said container and after it has been agitated infsaid receptacle.

' In a devi'ce ot' the typefdescribed, the combination of a liquid container, '.a burner for supplying heat to liquid in said, con

tain'er, means for supplying equal volumes of liquid and gas to saidcontainerand; burn ei respectively, ,a mixing receptacle communicating-Withs'aid container andhaving:

aliquid'outlet, meansifor agitating the liquid in said receptacle, and indicating means 'responsive tothe temperature of the liquid be fore it has beenheate( i in said container and after it 'has been agitated in said receptacle} *7; In-a device for the type described, a

liquid container havingan inlet a'nda'noutlet, means for-supplying heat to said container, a' receptaclecommunicating with the outlet of'said container, means for-causing liquid to 'flovv through said container and i into said receptacle, and means for introducing air into saidreceptacleto agitate the liquid therein andproduce a' substantially uniform temperature throughout the same. 8. In adevi'ce of the typefdescribed, aliqu d -dontamer havingan'inletand an outlet, means for supplying heat to said container, a receptacle, a liquid conduit connecting the outlet of said container with said receptacle, means for causing liquid to flow from said container into said receptacle through saidconduit, adjustable means for introducing air into said conduit to regulate the flow of liquid through the same, and to agitate the liquid in said receptacle to produce a substantially uniform temperature throughout the same.

9. In a device of the type described, a liquid container having an inlet and an out let, means for supplying heat to said container, a receptacle, a liquid conduit connecting the outlet of said container with said receptacle, means for causing liquid to flow from said container into said receptacle through said conduit, adjustable means for introducing air into said conduit to regulate the flow of liquid through the some, and means comprising a pipe extending from said conduit into the interior of said receptacle introducing this air into the body of the liquid within said receptacle.

10. In a device of the type described, the combination of a closed liquidreceptacle, a pipe for introducingliquid into the receptacle, said pipe having an outlet at a certain level within the receptacle, an outlet pipe communicating with the interior of the receptacle above this level and extending downward to produce a siphoning action, and means for admitting a restricted amount ofair into the pipe which introduces liquid into the receptacle. 7 7

- '11. In a device of the type described, the combination of means for supplying a liquid, means for bringing the liquid to a predetermined temperature, a container adapted to receive this liquid, a gas burner for supplying heat to the liquid in said container, and means for supplying to the burner a volume of combustible gas bearing a predetermined relation to the volume of liquid heated in said container. r

12. In a device of the type described, the combination of means for supplying a liquid, means for bringing the liquid to a predetermined temperature, a container adapted to receive this liquid, a gas burner for supplying heat to the liquid in said container, means for supplying combustible gas, means for bringing this gas to a predetermined'temperature, and means for supplying to'the burner'a volume of this gas bearing a predetermined relation to the'volume of liquid heated in said container.

13. In a device of the type des cribed,'the1 combinationof means for supplying a liquid,

means for bringing the liquid to a predeter mined temperature, 'a container adapted to receive this liquid, a gas burner for supplying heat to the liquid in said container, means for supplying combustible gas, means for bringing this gas to a temperature approximately equal to the said predetermined temperature and means for supplying to the burner a volume of this gas bearing a predetermined relation to the volume of liquid heated in said container.

14. In a device of the type described, the combination of means for supplying a liquid, means for preheating the liquid to a predetermined temperature, a container adapted to receive the preheated liquid, a gas burner for supplying heat to the liquid in said container, means for supplying combustible gas, means for bringing this gas into heat exchanging relation to the preheated liquid to equalize the temperatures of the gas and liquid, and means for supplying to the burner a volume of this gas bearing a predetermined relation to the volume of liquid heated in said container.

In a device of the type described, the combination of two containers, means for supplying a predetermined volume of liquid to one container, means for bringing a combustible gas to a predetermined temperature and pressure and for supplying to the other.container a substantially equal volume of said gas, and means for burning this volume of gas in heat exchanging relation with the-said volume of liquid. j

16. In a device of the type described, the combination of two containers, means for supplying a liquid to one container, means for bringing a combustible gas to a predetermined temperature and pressure and for supplying'said gas to the second container, means for burning this gas in heat exchanging relation with'said liquid, means for supplying liquid to the second container to take, the place of the gas previously supplied thereto, means'forsu pplying gas at the said predetermined temperature and pressure to the first container to take the place of the liquid previously supplied thereto, and means for subjecting the gas and liquid supplied to said first and second containers respectively to the action of the means for burning gas in heat exchanging relation with a liquid.

In a device of the type described, the combination of two containers of equal capacity,'mean s for supplying a liquid to one container, means for bringing a combustible gas to a predetermined temperature and pressure and for supplying said to the second container, a liquid heater, a gas burnor for said heater, pipe eonn ctions between said heater and burner and said containers, whereby gas from one container can be an lized in heating the liquid from the other.

18. In a device of the type described, means for bringing a combustible gas to a substantially constant predetermined temperature and'pres'sure,'means for supplying a liquid, two containers, aliquid heater, :1 burner for said heater, pipe connections between'the gas (all heater from said containers, so that the gas can be alternately supplied to said containers and substantially continuously, supplied to said burner from said containers. v

19. In a device of the type described, the

combination of means for supplying a combustible gas and a liquid, means for bringing the gas and liquid to substantially the same temperature, two containers, means for supplying the gas and liquid alternately to each, container, means for controlling the pressure at which the gas is suppliedto said containers, a liquid heater,-a burner for said heater, and means for conducting gas and 1 liquid from said containers to said burner and heater respectively. p

20. In a device of the type described, the combination of means for supplying acombustible gas and a liquid, means for bringing the gas and liquid to substantially the same temperature, two containers, means for supplying the gas and liquid alternately to each container, means for controlling the pressure at which the gas is supplied to said containers, a liquid heater, a burner for said heater, pipe" connections between said containers and the heater and burner, valves for controlling the flow of gas and liquid to'the I burner and heater respectively, and means responsive to changes in the liquid level in either of said containers for actuatingsaid valves. 1 a

21 In a device of thety'pe described, the combination ofme'ans for supplying a combustible gas and a liquid, means for bringing the 'gas and liquid to substantially the same temperature, two containers, means for supplying the gas and liquid alternately'to eachcontainer, means for controlling the pressure at which the gas'is suppliedito said con tainers, a'liquid heater, a burner for said heater, pipe connectionsbetween said containers andthe heater and burner, valves for controlling'the flow of gas and liquid to the burner andheater respectively, a motor for actuating said valves, and a float switch in each of said containers for controlling the operation of said motor.

22;"In a device of the type described, the combination of means for measuring definite relative volumes of gas and liquid, a

' rotatable valve for controlling the flow of (at least one of said fluids, an electric motor for operating said valve, and a float valve for-controlling the operationof said motor.

been rotated through a predeterir nod 23. In a device of the type described, the combination of a fluid container, a rotatable valve member for controlling the flow of fluid from said container, an electric motor for rotating sa d valve, a circuit for said motor, means actuated by said motor for arresting movement of said valve ithas angle, a float switch within said container iqr closingthe motor circuit to rotate the valve, and to open the motor circuit after movement-oi the valve has been arrested, locking means for said valve, and resilient means arranged so to be placed under tension by operation of'the motor and adapted to momentarily release the valve and actuate the said locking means. i

24. Ina device of the type described, the

combination of a fluid container, a rotatable valve member for controlling the flow of: fluid from said container, an electric motor for rotating said valve, a circuit for said motor, means actuated by said motor for arresting movement of? said valve after it has been rotated through a predetermined angle, afloat switch within said container for closing the motor circuit to rotate the valve, and to open themotor circuit after movement oi? the valve has been arrested, locking means for said valve, and resilient meansarranged so as to be placed under tension by operation of the motor and adapted to momentarily release the valve and actuate the said locking means, the" said locking means being constructed and arranged so that when the same is actuated it rotates the valve through a small angle and then locks the valve. V

In a device of the type described, the combination of a liquid container, aplurality of pipes within said container forming gas fines within which moisturemay'condense, a burner for supplying hot gases to said fiues, means for supplying a liquid to said containenuneane for supplying a combustible gas to said burner, means for measuring the amountsot liquid and gas supplied to said container and burner respectively, indicating means responsive to the temperature the liquid before and after it is heated in said container, and means for measuring the moisture condensed within said flues. 26. In device of the type described, the

combination oi acontain'er, meansfor alter.

' temperature, means for bring number of times and liquid to said container.

28. In device of the i pe described, the combination of a container, means for supplying two separate fluids, nuid connections communicating with said cont iner and with the means for supplying two separate fluids, a rotatable valve member for controlling the supply o'l these fluids to said container in such a manner that they are alternately supplied thereto, and means for indicating the number of revolutions of the said valve member whereby the total volume of cit ier iiuid supplied to said container can he ascertai ed.

29. In a device of the t p .1 cribed, the combination of a container, means for bringing a gas and liquid to subsrz itially the same ing the gas to a predetermined pressure, means for alternately supplying to said container predetermined volumes of this liquid, and of this gas, and means for indicating the number of times gas and liquid are supplied to said container.

30. In a device of the type described, the combination of two containers, means for bringing a gas to a predetermined temperature and pressure, means for continuously supplying to each of said containers in succession predetermined volumes of a liquid and of said gas, and means for indicating the number 01 times gas and liquid are supplied to said container.

81. In a device of the type described, the combination of two containers, each having a gas port near the top thereof and a liquid port near the bottom thereof, pipe connect-ions communicating with said gas and liquid ports, a single valve member for controlling the flow Off gas and liquid through said pipe connections so that gas and liquid can be alternately supplied to each container, and

means responsive to movement oi said valve member for indicating the number oi times gas and liquid are supplied to said containers.

32. In a device of the type described, the combination of two containers, pipe connections communicating with each container for supplying a gas and a liquid thereto, valves for controlling the supply of and liquid to said containers, a motor tor operating ai valves, a float switch in each of said contain ers for controlling the operation 01" said motor, and means for indicating the number of times and liquid are supplied to'said containers.

33. In a device of the type described, the combination of a container, means for bringing a gas to a predetermined temperature and pressure, means for alternately supplying to said container predetermined volumes of a liquid and of said gas, a single rotatable valve member for controlling the supply 01 gas and liquid to said container, means for actuating said valve, and means responsive to the movement of said valve for indicating the quantity of each fluid supplied to said container.

34-. In a device oi the type described, the combination of two containers, means for bringing a gas to a predetermined temperature and Pie sure, means for alternately supplying to said containers predetermined volumes of a liquid and of said gas, means for independently regulating the flow oi liquid into each of said containers, and means for indicating the number of times gas and liquid are supplied to said containers.

In a device of the type described, the combination of two containers, means for bringing a gas to predetermined temperature and pressure, means for alternately supplying to each cit said containers predetermined volumes ot a liquid and of said gas, means adapted to indicate the number of times and liquid are supplied to said containers, anc means for circulating the said liquid through said containers.

36. A method of non-intermittently determining the calorific value of a gas which comprises burning the gas in heat interchanging relation with a volume of water proportionate to the volume of gas burned, continuously feeding the gas to be burned by displacing the gas from a container with the water being heated, and registering the rise in temperature of the water due to the combustion of the said gas in units corresponding to the heat value of the gas.

37. A method for determining the calorific value of a gas comprising continuously burning gas in heat transferring relationship with water, maintaining a definite proportional relation of the water heated to the gas burned by using the water to control the volume of gas burned so as to attain a substantial temperature rise of the said water, and indicating the heat value of the gas as reduced to standard volume pressure conditions.

38. A gas calorimeter having in combination a heat absorption chamber, means for burning gas in said chamber, means for automatically and non-intermittently supplying gas to said burning means, means for nonintermittently and. automatically passing water through the said chamber in amounts equal in volume to the volume of gas being burned, and means forvautomatically indicating the change in temperature of the said water in passing through the said chamber.

39. A method of determining the calorific value of gas which comprises burning gas in heat interchanging relation with water, continuously measuring the water prior to its being heated, continuously measuring the gas being burned by displacing the gas with the measured water volume for volume, and continuously recording the rise in temperature of the water due to the heat of combustion of the gas in terms of the B. t. u. value of the gas.

40. A method of determining the calorific value of gas which comprises burning gas in heat interchanging relation with water, continuously supplying gas to the burners in a volume equal to the volume of water being heated, utilizing thewater prior to its being heated to measure the gas, and continuously recording the rise in temperature or the water due to the heat of combustion of the gas in units corresponding to the heat value or the gas.

41. A method of determining the calorific value of gas which comprises burning gas in heat transferring relation with water, supplying the gas and water to a container wherein they contact one another, simul taneously and continuously withdrawing the gas and water from the'container in measured portions by displacing the gas with the water volume for volume, and recording the rise in temperature of the water due to the heat of combustion of gas in units corresponding to the heat value of the gas. J

42. A method of determining the. calorific value of gas which comprises burning gas in heat interchanging relation with water, continuously measuring the water being heated, continuously measuring the gas being burned by displacing the gas with. the measured water volume for volume, equalizing the pressure of the measured gas and water and then sending them to the burner and heat interchanger respectively, and recording the rise in temperature of the water due to the heat of combustion of the gas in units corresponding to the heat value of t 1e 'as.

A method of determining the calorific value of gas which comprises burning gas in heat interchanging relation with a water, equalizing the pressure of water being heated with the pressure of gas being burned, and continuously measuring the volume of gas and water while under the same pressure by displacing the gas volume for volume with the measured volumes of water, and recording the rise in temperature of water due to the heat of combustion of gas in units corresponding to the heatvalue of the gas.

44. In a gas calorimeter, a combustion chamber having a gas burner therein, a water chamber mounted in heat interchanging relation to the combustion chamber, means for measuring the rise in temperature of the Water passing through the water chamber, and means for measuring the water and gas prior to passing to their respective chambers, comprising means for continuously measuring separate volumes of gas and water that have a definite proportional relationship to one another while using the water for displacing the gas being measured.

45. In a gas calorimeter, a combustion chamber having a burner therein, a water chamber mounted in heat interchanging relationship to the combustion chamber, means for measuring the rise in temperature of the waterpassing through the water chamber, a displacement meter for continuously measuring separate volumes of gas and water having a definite proportional relationshipto one another, and means for separately conducting the measured. gas and water to the burner and water chamber respectively.

46. In the art of determining the heating value of gas, the steps of bringing the gas to a predetermined temperature, flowing and measuring the gas in contact with a stream of water at constant temperature to maintain the gas at constant temperatures, burning said gas and transferring the heat of said burning to said water, and maintaining said gas at constant density at't-he point of measuring it.

47. In the art of determiningthe heating value of gas, the steps of bringing the gas to a predetermined temperature, measuring the gas at constant density and humidity, burning said gas in heat transferring relation to flowing water, and measuring the increase in temperature of said water.

48. In the art of determining the heating. value of gas, the steps of bringing the gas to a predetermined temperature, measuring the gas at constant density and temperature, metering said gas in contact with water flowing in the same direction as the gas to maintain the humidityof the gas constant, and burning said gas in heat transferring relation to said water.

49. In the art of determining the heating value of gas, the steps of maintaining the density and temperature of the gas constant, metering the gas in contact with astream of water flowing in the same direction as the gas to maintain-the humidity of the gas constant, burning said gas in heat transferring relation to said water, and registering the heat value of the gas in a continuous manner.

50. A calorimeter apparatus comprising in combination means for heating water by gas whose calorific value is to be determined, means for measuring gas and water in constant proportions, connections between said measuring means and said heating means, means for registering the calorific value of the gas, said connections and said measuring .means having only sufiicient volumetric capacity'to maintain a continuous flow of gas to said. heating means, whereby a minimum lag between a given change in the calorific value of the gas and the registration of said change is provided.

In testimony whereof I affix my signature.

SAMUEL W'. FARR. 

